Attempts to synthesise quaternary MAX phases (Zr,M)2AlC and Zr2(Al,A)C as a way to approach Zr2AlC

Denis Horlait; Salvatore Grasso; Alexander Chroneos; William E. Lee

doi:10.1080/21663831.2016.1143053

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Attempts to synthesise quaternary MAX phases (Zr,M)2AlC and Zr2(Al,A)C as a way to approach Zr2AlC

Reports | 更新时间：2026-08-19

- Attempts to synthesise quaternary MAX phases (Zr,M)2AlC and Zr2(Al,A)C as a way to approach Zr2AlC
- Materials Research Letters Vol. 4, Issue 3, Pages: 137-144(2016)
- 作者机构：
  
  1. Department of Materials and Centre for Nuclear Engineering Imperial College London
  2. School of Engineering and Material Science Queen Mary University of London
  3. Faculty of Engineering and Computing Coventry University
- 作者简介：
- 基金信息：
- DOI：10.1080/21663831.2016.1143053
  CLC：
- Online First：09 February 2016，
  
  Published：2016
- 稿件说明：
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Denis Horlait, Salvatore Grasso, Alexander Chroneos, et al. Attempts to synthesise quaternary MAX phases (Zr,M)2AlC and Zr2(Al,A)C as a way to approach Zr2AlC[J]. Materials Research Letters, 2016, 4(3): 137-144.
DOI：

Denis Horlait, Salvatore Grasso, Alexander Chroneos, et al. Attempts to synthesise quaternary MAX phases (Zr,M)2AlC and Zr2(Al,A)C as a way to approach Zr2AlC[J]. Materials Research Letters, 2016, 4(3): 137-144. DOI： 10.1080/21663831.2016.1143053.

摘要

Abstract

Despite having never been synthesized

the MAX phase Zr

AlC attracts a lot of interest owing to its foreseen properties. A possible way to circumvent this obstacle is to stabilize Zr

AlC by partially substituting one of its constituting elements. Here we report on attempts to synthesise quaternary MAX phases (Zr

AlC and Zr

(Al

A)C where M = Cr

Ti or Mo and A = S

Sb and Pb. We were notably able to produce Zr

(Al

0.2

0.8

(Al

0.35

0.65

and Zr

(Al

0.3

0.7

with the latter representing the first antimony-based MAX phase ever reported.

Impact Statement

: Numerous syntheses of Zr

AlC derived compositions were attempted. Zr

(Al

0.2

0.8

(Al

0.35

0.65

)C and Zr

(Al

0.3

0.7

)C were notably produced and reported for the first time.

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Related Institution

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e Ernst Ruska-Centre for Microscopy and Spectroscopy with Electrons

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