1. Ningbo Institute of Materials Technology and Engineering Chinese Academy of Sciences Ningbo Zhejiang People’s Republic of China
2. University of Chinese Academy of Sciences
3. Ningbo Institute of Materials Technology and Engineering Chinese Academy of Sciences Ningbo
4. Department of Physics and Astronomy University of North Carolina at Chapel Hill Chapel Hill
Online First:13 June 2017,
Published:2017
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Youhu Chen, Yunpeng Li, Yuanfei Wang, et al. Thin WS2 nanotubes from W18O49 nanowires[J]. Materials Research Letters, 2017, 5(7): 508-515.
DOI:
Youhu Chen, Yunpeng Li, Yuanfei Wang, et al. Thin WS2 nanotubes from W18O49 nanowires[J]. Materials Research Letters, 2017, 5(7): 508-515. DOI: 10.1080/21663831.2017.1337050.
BSTRACTSingle- and double-walled WS
2
nanotubes of small diameter (10 nm) and few layers (4) have been synthesized by heating ultrathin W
18
O
49
nanowires and S powders in an H
/Ar atmosphere at 840°C. In the process of formation and growth of a WS
nanotube
the W
phase transformed first into an amorphous WS
3
structure via the absorption and diffusion of the sulfur atoms to substitute the oxygen atoms
and followed by a phase transition from amorphous WS
to 2H-WS
by losing sulfur atoms to form the shell of the WS
nanotube.
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