BSTRACT

Bcc

-ordered B2 and

fcc

phases manifest three different orientation relationships (ORs) in the same microstructure: Kurdjumov–Sachs

Nishiyama–Wasserman and Pitsch. This unique microstructure was developed via conventional cold-rolling and subsequent annealing of an

fcc

-based Al

0.3

CoCrFeNi complex concentrated alloy (CCA). The degeneracy in crystallographic ORs was caused by {111}⟨112⟩twins

on multiple {111}

from the prior cold-rolling step. Annealing produced B2 precipitates on all the major

fcc

slip-systems by heterogeneously nucleating B2 at twin-matrix interfaces and twin–twin intersections. Such a precipitation-hardenable microstructure is expected to increase the strength of

fcc

-based CCAs by effectively blocking 1/2⟨110⟩and 1/6⟨112⟩mobile dislocations.

Impact statement

Three different

fcc

-B2 orientation relationships (ORs) were observed for the first time in complex concentrated alloys. Such degenerate ORs in B2 precipitation can potentially block dislocation on multiple slip planes.