HAN Jingyi, LIU Songsong, SUN Yu, et al. Interface reaction and research progress of blended-salts in lithium batteries[J]. 2021, 53(2): 22-32.
DOI:
HAN Jingyi, LIU Songsong, SUN Yu, et al. Interface reaction and research progress of blended-salts in lithium batteries[J]. 2021, 53(2): 22-32.DOI: 10.11918/202007012.
Interface reaction and research progress of blended-salts in lithium batteries
To improve the energy density of lithium (Li) batteries and solve the problems of conventional single-salt electrolytes such as poor thermal stability
low conductivity
and Li dendrites
developing new blended-salts electrolytes has become an important research direction of Li battery electrolytes. Blended-salts can change the ion conductivity
Li ion solubility
viscosity
and other properties of the solution
and can improve the electrochemical performance of the battery by affecting the interface of electrode and electrolyte as well as the surface and interface of electrode materials. This paper collects the latest research literature at home and abroad
and reviews the research progress of blended-salts electrolytes for Li batteries
including different research directions such as Li ion batteries
Li metal batteries
Li sulfur batteries
and solid state batteries. The advantages and disadvantages of commonly used single-salts are summarized
the effects and mechanism explanations of hybrid electrolytes on different surface interfaces of batteries are elaborated
and the applications of blended-salts in different battery systems are analyzed. At last
the existing problems of blended-salts electrolytes and interface reactions are discussed
and the development direction and application of characterization of novel blended-salts and interface reactions are given. The current research studies of blended-salts are mostly limited to performance improvement and its mechanism needs to be further investigated. The existing explanation usually unfolds from single-salts
and the mechanism of synergistic effect of blended-salts is an important research direction in the future.