Numerical simulation of the effect of H2S on CH4 ignition delay and NO reduction

SUN Qiaoqun; WANG Yide; GAO Jianmin; DU Qian; WU Shaohua

doi:10.11918/j.issn.0367-6234.201809150

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Numerical simulation of the effect of H2S on CH4 ignition delay and NO reduction

更新时间：2026-10-23

- Numerical simulation of the effect of H2S on CH4 ignition delay and NO reduction
- Vol. 51, Issue 7, Pages: 49-55(2019)
- 作者机构：
  
  1. 哈尔滨工程大学航天与建筑工程学院,哈尔滨,150001
  2. 哈尔滨工业大学燃烧工程研究所,哈尔滨,150001
  3. 山东省特种设备检验研究院有限公司,济南,250101
- 作者简介：
- 基金信息：
- DOI：10.11918/j.issn.0367-6234.201809150
  CLC： TK16
- Published：2019
- 稿件说明：
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SUN Qiaoqun, WANG Yide, GAO Jianmin, et al. Numerical simulation of the effect of H2S on CH4 ignition delay and NO reduction[J]. 2019, 51(7): 49-55.
DOI：

SUN Qiaoqun, WANG Yide, GAO Jianmin, et al. Numerical simulation of the effect of H2S on CH4 ignition delay and NO reduction[J]. 2019, 51(7): 49-55. DOI： 10.11918/j.issn.0367-6234.201809150.

摘要

为探究硫化氢(H2S)在常压范围内对甲烷(CH4)燃烧特性的影响

采用化学动力学软件CHEMKIN-PRO中的0-D和PFR反应器研究H2S浓度、过量空气系数、压力和温度对CH4点火延迟及还原NO的影响

并通过敏感性和生成率分析揭示其化学动力学机理. 模拟结果表明:H2S的存在促进活性基团(H

HO2

HO2和H2O2)的生成速率

从而缩短预混气点火延迟时间

且在低温下的影响作用更加明显；预混气点火延迟时间随着过量空气系数的增大而减小；压力增加亦有利于缩短点火延迟时间. H2S可降低CH4/H2S还原NO的温度

主要由于H2S降低CH4的反应温度

使还原性基团CHi在较低温度下产生；但同时H2S的存在

在一定程度上降低NO的还原效率

且在贫氧气氛中的影响更为显著.

Abstract

To investigate the effects of hydrogen sulfide (H2S) on the combustion characteristics of methane (CH4) in atmospheric pressure range

the 0-D and PFR reactors were adopted in CHEMKIN-PRO chemical kinetics software to investigate the effects of H2S concentration

excess air coefficient

pressure and temperature on CH4 ignition delay and NO reduction

meanwhile sensitivity analysis was used to reveal the chemical kinetics mechanism. The modeling results showed that the H2S could promote the formation rate of active groups (H

HO2

H2O2)

so premixed gas ignition delay time was reduced

and the effect was more obvious at low temperature. The premixed gas ignition delay time is decreased with the increase of excess air coefficient and pressure. The H2S decreases the CH4 reaction temperature and reductive group CHi are generated at lower temperature

so the H2S decreases the temperature of NO reduction by CH4/H2S. But the existing of H2S reduces NO reduction efficiency to a certain extent

and the effect is more remarkable in fuel-rich atmosphere.

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