Darin J. Tallman, Babak Anasori, Michel W. Barsoum. A Critical Review of the Oxidation of Ti2AlC, Ti3AlC2 and Cr2AlC in Air[J]. 材料研究快报(英文), 2013,1(3):115-125.
Darin J. Tallman, Babak Anasori, Michel W. Barsoum. A Critical Review of the Oxidation of Ti2AlC, Ti3AlC2 and Cr2AlC in Air[J]. Materials Research Letters, 2013, 1(3): 115-125.
Darin J. Tallman, Babak Anasori, Michel W. Barsoum. A Critical Review of the Oxidation of Ti2AlC, Ti3AlC2 and Cr2AlC in Air[J]. 材料研究快报(英文), 2013,1(3):115-125.DOI: 10.1080/21663831.2013.806364.
Darin J. Tallman, Babak Anasori, Michel W. Barsoum. A Critical Review of the Oxidation of Ti2AlC, Ti3AlC2 and Cr2AlC in Air[J]. Materials Research Letters, 2013, 1(3): 115-125.DOI: 10.1080/21663831.2013.806364.
A Critical Review of the Oxidation of Ti2AlC, Ti3AlC2 and Cr2AlC in Air
the most resistant to oxidation in air in the 900–1
400°C temperature range are Ti
2
AlC
Ti
3
AlC
2
and Cr
2
AlC. A literature review
however
shows that whil
e many claim the oxidation kinetics to be parabolic
others claim them to be cubic. Whether the kinetics are parabolic or better is of vital practical importance. By carefully re-plotting the results of others and carrying out one oxidation run for ≈3
000 h at 1
200°C on a Ti
2
AlC sample
we conclude that the oxidation kinetics are better described by cubic kinetics and that even that conclusion is an approximation. Lastly
we present compelling evidence that the rate-limiting step during the oxidation of Ti
2
AlC is diffusion down the alumina scale grain boundaries.
Abstract
Of all the M
n
+1
AX
n
phases
the most resistant to oxidation in air in the 900–1
400°C temperature range are Ti
2
AlC
Ti
3
AlC
2
and Cr
2
AlC. A literature review
however
shows that while many claim the oxidation kinetics to be parabolic
others claim them to be cubic. Whether the kinetics are parabolic or better is of vital practical importance. By carefully re-plotting the results of others and carrying out one oxidation run for ≈3
000 h at 1
200°C on a Ti
2
AlC sample
we conclude that the oxidation kinetics are better described by cubic kinetics and that even that conclusion is an approximation. Lastly
we present compelling evidence that the rate-limiting step during the oxidation of Ti
2
AlC is diffusion down the alumina scale grain boundaries.
a Beijing Key Laboratory of Microstructure and Property of Advanced Materials Faculty of Materials and Manufacturing Beijing University of Technology
b Department of Mechanical Engineering The University of Western Australia
a Beijing Key Laboratory of Microstructure and Property of Advanced Materials Faculty of Materials and Manufacturing Beijing University of Technology Beijing People’s Republic of China
c Science and Technology on Advanced High Temperature Structural Materials Laboratory Beijing Institute of Aeronautical Materials
d State Key Laboratory of Silicon Materials Department of Materials Science and Engineering Zhejiang University