1. 东北林业大学 工程技术学院,哈尔滨,150040
2. 先进焊接与连接国家重点实验室(哈尔滨工业大学),哈尔滨,150001
纸质出版:2021
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李春伟, 田修波, 姜雪松, 等. 外部磁场对电-磁场协同增强HiPIMS放电及V膜沉积与性能的调制[J]. 哈尔滨工业大学学报, 2021,53(8):144-152.
LI Chunwei, TIAN Xiubo, JIANG Xuesong, et al. Modulation of external magnetic field on (EMF) HiPIMS discharge,deposition, and properties of vanadium films[J]. 2021, 53(8): 144-152.
李春伟, 田修波, 姜雪松, 等. 外部磁场对电-磁场协同增强HiPIMS放电及V膜沉积与性能的调制[J]. 哈尔滨工业大学学报, 2021,53(8):144-152. DOI: 10.11918/202003093.
LI Chunwei, TIAN Xiubo, JIANG Xuesong, et al. Modulation of external magnetic field on (EMF) HiPIMS discharge,deposition, and properties of vanadium films[J]. 2021, 53(8): 144-152. DOI: 10.11918/202003093.
为了获得新型HiPIMS稳定放电及制备优质膜层时的最优外部磁场参数
研究外部磁场变化对电-磁场协同增强高功率脉冲磁控溅射((E-MF)HiPIMS)放电及沉积特性的调制过程。在其他工艺参数保持不变的情况下
研究了外部磁场(线圈电流)对HiPIMS钒(V)靶放电规律以及V膜微观结构和性能的影响。采用数字示波器监测HiPIMS放电行为
利用XRD、SEM、AFM、摩擦磨损试验机及电化学腐蚀法等表面分析方法
研究V膜相结构、表面形貌、截面形貌、耐摩擦磨损性能及耐腐蚀性能等沉积特性。结果表明:随线圈电流的增加
基体离子电流密度逐渐增加
当线圈电流为6 A时基体离子电流密度最高可达209.2 mA/cm2。V膜的相结构仅为V(111)但其晶面衍射峰强度随线圈电流的增加而逐渐增加。V膜表面呈现出典型的圆凹坑状形貌特征
其表面粗糙度先减小后增大且最小仅为10 nm。当线圈电流(<4 A)较低时V膜生长表现为致密细小的晶体生长结构
膜层沉积速率随着线圈电流的增加而增加。当线圈电流为4 A时
V膜样品的摩擦系数最小、耐磨性最优
同时V膜样品具有最好的耐蚀性。
The optimal external magnetic field parameters for stable discharge of a novel HiPIMS and obtaining high-quality film were explored
and the modulation of the external magnetic field on the discharge and deposition characteristics of electro-magnetic fields synergistically enhancing high power impulse magnetron sputtering ((E-MF) HiPIMS) was studied. The effects of coil current of external magnetic field on the discharge of HiPIMS vanadium target as well as the microstructure and properties of vanadium films were investigated. The discharge behavior of HiPIMS was monitored
and the influences of external magnetic field on the phase structure
surface morphology
cross-section morphology
friction and wear resistance
and corrosion resistance of vanadium films were studied by XRD
SEM
AFM
friction and wear tester
and electrochemical corrosion method. Results show that with the increase of the coil current
the substrate ion current increased gradually. When the coil current was 6 A
the maximum substrate ion current density reached 209.2 mA/cm2. The phase structure of vanadium film was only V (111)
but the intensity of its diffraction peak increased with the increase of coil current. The surface of vanadium film exhibited typical round-pit shape. The surface roughness decreased first and then increased
and the minimum was only 10 nm. At low coil current (<4 A)
the vanadium film showed a compact and fine crystal growth structure. With the increase of coil current
the deposition rate of the film increased gradually. When the coil current was 4 A
the friction coefficient of the vanadium film was the smallest
the wear resistance was the best
and the vanadium film samples had the best corrosion resistance.
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