1. 水质科学与水环境恢复工程北京市重点实验室(北京工业大学),北京,100124
2. 城市水资源与水环境国家重点实验室(哈尔滨工业大学),哈尔滨,150090
纸质出版:2022
移动端阅览
李冬, 刘名扬, 张杰, 等. 水力筛分间歇饥饿CANON工艺参数调控及稳定运行[J]. 哈尔滨工业大学学报, 2022,54(2):1-7.
LI Dong, LIU Mingyang, ZHANG Jie, et al. Optimization and stable operation of CANON process of intermittent starvation based on hydraulic screening[J]. 2022, 54(2): 1-7.
李冬, 刘名扬, 张杰, 等. 水力筛分间歇饥饿CANON工艺参数调控及稳定运行[J]. 哈尔滨工业大学学报, 2022,54(2):1-7. DOI: 10.11918/202102040.
LI Dong, LIU Mingyang, ZHANG Jie, et al. Optimization and stable operation of CANON process of intermittent starvation based on hydraulic screening[J]. 2022, 54(2): 1-7. DOI: 10.11918/202102040.
为探究水力筛分间歇饥饿策略运行CANON工艺的稳定性及相关参数的设置
采用SBR反应器运行CANON工艺
定期通过水力筛分排出絮状污泥
之后对其进行间歇饥饿
以此抑制NOB的生长繁殖
探讨沉降时间和饥饿周期两项参数的调控
实现CANON工艺处理低氨氮污水的稳定运行。结果显示
不同的沉降时间对于粒径分布和功能菌活性有较大影响
1.5 min以上的沉降时间可将ANAMMOX菌基本留存在反应器中
AOB在颗粒污泥和絮状污泥中均有分布
NOB则主要分布于传质阻力小的絮状污泥中。AOB在缺氧饥饿期间的活性衰减速率基本保持稳定
而NOB在面对缺氧饥饿时表现得更为敏感
活性衰减速率大于AOB。在恢复阶段
由于AOB具有一种独特的机制来应对饥饿
能够将细胞保持在经历短时饥饿后立即以最大速率开始氧化NH+4-N的状态
使其在恢复3 d时的底物降解速率就达到0.097 g/(g·d)
恢复至饥饿前的86%
而NOB因无法快速适应环境的变化活性恢复速率滞后于AOB。采用4 d饥饿和3 d恢复的模式运行反应器
NOB得到有效抑制
出水NO-3-N呈现下降趋势
之后调整间歇饥饿周期为4 d饥饿和5 d恢复
更好地提升了AOB的活性
处理效果进一步提升
进入稳定阶段
出水NH+4-N和NO-3-N平均值分别为2.69和7.79 mg/L
氨氮去除率和总氮去除率分别达到96%和79%。采用水力筛分间歇饥饿CANON工艺处理低氨氮污水运行性能稳定
出水满足GB 18918—2002《城镇污水处理厂污染物排放标准》中所规定的一级A标准。
In order to explore the stability of the completely autotrophic nitrogen removal over nitrite (CANON) process and the setting of related parameters in the intermittent starvation based on hydraulic screening
sequencing batch reactor (SBR) was used for the CANON process. Flocculent sludge was periodically discharged through hydraulic screening
and intermittent starvation was performed on it to inhibit the growth and reproduction of nitrite-oxidizing bacteria (NOB). The adjustment of two parameters (sedimentation time and starvation period) was investigated to realize the stable operation of CANON process. Experimental results show that sedimentation time had great impact on the particle size distribution and functional bacteria activity. A sedimentation time of more than 1.5 min could basically retain the ANAMMOX bacteria in the reactor. Ammonia-oxidizing bacteria (AOB) were distributed in flocculent sludge and granular sludge
and NOB was mainly distributed in the flocculent sludge with low mass transfer resistance. The activity decay rate of AOB during hypoxic starvation remained basically stable
while NOB was more sensitive in the face of hypoxic starvation
and the activity decay rate of NOB was greater than that of AOB. In the recovery phase
since AOB has a unique mechanism to deal with starvation that it can keep the cells in a state of oxidizing NH+4-N at the maximum rate immediately after experiencing a short-term starvation
it could reach the substrate degradation rate of 0.097 g/(g·d) when the inlet water has been fed for 3 d
which was 86% of the pre-starvation rate. However
NOB could not quickly adapt to the changes in the environment
causing its activity recovery rate to lag behind AOB. When the reactor was operated in the mode of 4 d starvation and 3 d recovery
NOB was effectively suppressed that the NO-3-N in the effluent showed a downward trend. Afterwards
the intermittent starvation period was adjusted to 4 d starvation and 5 d recovery
which improved the activity of AOB and the treatment effect was further enhanced. Entering the stable stage
the average values of effluent NH+4-N and NO-3-N were 2.69 and 7.79 mg/L respectively
and the removal rates of ammonia nitrogen and total nitrogen reached 96% and 79% respectively. The use of hydraulic screening and intermittent starvation CANON process to treat low-ammonia nitrogen wastewater has stable operation performance
and the effluent meets the first-level A standard specified in the Discharge Standard of Pollutants for Municipal Wastewater Treatment Plant (GB 18918—2002).
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