JIA Zhigang, KONG Delong, WANG Minghao, et al. Metallization process of PA10T with chrome-free roughening and palladium-free activation[J]. 2017, 49(5): 2017-5.
JIA Zhigang, KONG Delong, WANG Minghao, et al. Metallization process of PA10T with chrome-free roughening and palladium-free activation[J]. 2017, 49(5): 2017-5.DOI: 10.11918/j.issn.0367-6234.201611017.
In order to replace the traditional pretreatment process for electroless plating of chromic acid roughening and colloid palladium activation
the metal layer was prepared on the surface of nylon (PA10T) through a green method. The distribution of functional groups and the change of valence bonds on the nylon surface were characterized by Fourier transform infrared spectrometry and X ray photoelectron spectrometry
and then a model was established to illustrate the metallization process. The results show that the roughening system of sulphuric acid-ethanol can be used to achieve the effect of roughening
make the amide bond rupture and generate amino and carboxyl in PA10T. When the palladium-free activation process is adopted
the surface activation of nylon could be achieved by the coordination of Cu2+ with amino groups and carboxyl groups. The simple and environmentally friendly method mentioned above could get a good adhesion of the metal coating on the PA10T surface
the coating binding force reaches 537 N·cm-2 which is tested by electronic universal material testing machine.