RP⁃3航空煤油低温氧化特性的试验与数值计算

刘靖; 胡二江; 黄佐华; 曾文

doi:10.13224/j.cnki.jasp.20210074

Chinese

您当前的位置：

首页 >

文章列表页 >

RP⁃3航空煤油低温氧化特性的试验与数值计算

燃烧、传热、传质 | 更新时间：2025-04-07

- RP⁃3航空煤油低温氧化特性的试验与数值计算
- Experiment and numerical calculation on low⁃temperature oxidation characteristics of RP⁃3 aviation kerosene
- 航空动力学报 2022年37卷第1期页码：36-45
- 作者机构：
  
  1.西安交通大学能源与动力工程学院动力工程多相流国家重点实验室，西安 710049
  2.沈阳航空航天大学航空发动机学院辽宁省航空推进系统先进测试技术重点实验室，沈阳 110136
- 作者简介：
  
  刘靖（1995-），女，博士生，主要从事碳氢燃料基础燃烧特性研究。
  胡二江（1983-），男，教授，博士，主要从事航空发动机点火和燃烧调控研究。E⁃mail：hujjiang@mail.xjtu.edu.cn
- 基金信息：
  
  国家自然科学基金(91641124)
- DOI：10.13224/j.cnki.jasp.20210074
  中图分类号：
- 稿件说明：
移动端阅览
刘靖, 胡二江, 黄佐华, 等. RP⁃3航空煤油低温氧化特性的试验与数值计算[J]. 航空动力学报, 2022,37(1):36-45.

Jing LIU, Erjiang HU, Zuohua HUANG, et al. Experiment and numerical calculation on low⁃temperature oxidation characteristics of RP⁃3 aviation kerosene[J]. Journal of Aerospace Power, 2022, 37(1): 36-45.
刘靖, 胡二江, 黄佐华, 等. RP⁃3航空煤油低温氧化特性的试验与数值计算[J]. 航空动力学报, 2022,37(1):36-45. DOI： 10.13224/j.cnki.jasp.20210074.

Jing LIU, Erjiang HU, Zuohua HUANG, et al. Experiment and numerical calculation on low⁃temperature oxidation characteristics of RP⁃3 aviation kerosene[J]. Journal of Aerospace Power, 2022, 37(1): 36-45. DOI： 10.13224/j.cnki.jasp.20210074.

摘要

在射流搅拌反应器（JSR）中对压力为0.1 MPa、温度范围为550~1 100 K、当量比分别为0.5与1.0、滞留时间为2 s的工况条件下RP⁃3航空煤油及由正癸烷（摩尔分数为0.14）/正十二烷（0.1）/异十六烷（0.3）/甲基环己烷（0.36）/甲苯（0.1）组成的模型燃料的低温氧化过程进行了试验测试。同时，通过耦合基于反应类的全局敏感性分析方法、解耦法和遗传算法，构建了该模型燃料的简化反应动力学机理（181个组分和872个反应），并对模型燃料的低温氧化特性进行了数值计算。结果表明：模型燃料低温氧化过程中主要组分摩尔分数随温度的变化趋势与RP⁃3航空煤油吻合较好；构建的RP⁃3航空煤油模型燃料的简化反应机理可以较好地预测该模型燃料低温氧化过程中主要组分摩尔分数随温度变化的整体趋势，但在部分组分摩尔分数峰值及负温度系数（NTC）效应预测上尚存在偏差。

Abstract

The low⁃temperature oxidation of RP⁃3 aviation kerosene and its surrogate fuel （

⁃decane （mole fraction of 0.14）/

⁃dodecane （0.1）/iso⁃cetane （0.3）/methylcyclohexane（0.36）/toluene （0.1）），were experimentally tested in a jet stirring reactor （JSR） at the conditions of the pressure of 0.1 MPa，the temperature range of 550-1 100 K，the equivalence ratios of 0.5 and 1.0，and the residence time of 2 s.Meanwhile，through the reaction class⁃based global sensitivity analysis，decoupling methodology and multi⁃objective genetic algorithm，the reduced reaction kinetic mechanism of the surrogate fuel （including 181 species and 872 reactions） was established，and the low⁃ temperature oxidation characteristics of the surrogate fuel were simulated.The results showed that the temperature⁃dependent trends of the mole fractions of main species in the low⁃temperature oxidation process of the surrogate fuel were in good agreement with RP⁃3 aviation kerosene.The reduced reaction mechanism of the surrogate fuel for RP⁃3 aviation kerosene had a good prediction of the temperature⁃dependent trends of the mole fractions of main species during the low⁃temperature oxidation of the surrogate fuel.However，there were still some deviations in the prediction of the peak mole fractions and negative temperature coefficient （NTC） effect of some species.

关键词

Keywords

references

MASIOL M , HARRISON R M . Aircraft engine exhaust emissions and other airport⁃related contributions to ambient air pollution:a review [J]. Atmospheric Environment , 2014 , 95 : 409 ⁃ 455 .

MENSCH A , SANTORO R J , LITZINGER T A , et al . Sooting characteristics of surrogates for jet fuels [J]. Combustion and Flame , 2010 , 157 （ 6 ）: 1097 ⁃ 1105 .

KIM D , MARTZ J , VIOLI A . A surrogate for emulating the physical and chemical properties of conventional jet fuel [J]. Combustion and Flame , 2014 , 161 （ 6 ）: 1489 ⁃ 1498 .

MUNZAR J D , AKIH⁃KUMGEH B , DENMAN B M , et al . An experimental and reduced modeling study of the laminar flame speed of jet fuel surrogate components [J]. Fuel , 2013 , 113 : 586 ⁃ 597 .

ABIANEH O S , CHEN C P , MAHALINGAM S . Numerical modeling of multi⁃component fuel spray evaporation process [J]. International Journal of Heat and Mass Transfer , 2014 , 69 : 44 ⁃ 53 .

NARAYANASWAMY K , PITSCH H , PEPIOT P . A component library frame work for deriving kinetic mechanisms for multi⁃component fuel surrogates:application for jet fuel surrogates [J]. Combustion and Flame , 2016 , 165 : 288 ⁃ 309 .

ALEKSEEV V A , SOLOVIOVA‑SOKOLOVA J V , MATVEEV S S , et al . Laminar burning velocities of n ⁃decane and binary kerosene surrogate mixture [J]. Fuel , 2017 , 187 : 429 ⁃ 434 .

张英佳，黄佐华，王金华，等 . 激波管研究煤油/空气混合气的自着火特性 [J]. 科学通报， 2011 ， 56 （ 1 ）： 85 ⁃ 93 .

ZHANG Yingjia , HUANG Zuohua , WANG Jinhua , et al . Shock tube study on auto⁃ignition characteristics of kerosene/air mixtures [J]. Chinese Science Bull , 2011 , 56 （ 1 ）: 85 ⁃ 93 . （in Chinese）

ZHANG C H , LI B , RAO F , et al . A shock tube study of the autoignition characteristics of RP⁃3 jet fuel [J]. Proceedings of the Combustion Institute , 2015 , 35 （ 3 ）: 3151 ⁃ 3158 .

唐洪昌，张昌华，李萍，等 . 煤油自点火特性的实验研究 [J]. 物理化学学报， 2012 ， 28 （ 4 ）： 787 ⁃ 791 .

TANG Hongchang , ZHANG Changhua , LI Ping , et al . Experimental study of autoignition characteristics of kerosene [J]. Acta Physico⁃Chimica Sinica , 2012 , 28 （ 4 ）: 787 ⁃ 791 . （in Chinese）

MAO Y B , YU L , WU Z Y , et al . Experimental and kinetic modeling study of ignition characteristics of RP⁃3 kerosene over low⁃to⁃high temperature ranges in a heated rapid compression machine and a heated shock tube [J]. Combustion and Flame , 2019 , 203 : 157 ⁃ 169 .

CHEN B H , LIU J Z , YAO F , et al . Ignition delay characteristics of RP⁃3 under ultra⁃low pressure （0.01-0.1 MPa） [J]. Combustion and Flame , 2019 , 210 : 126 ⁃ 133 .

LIANG J H , WANG S , HU H H , et al . Shock tube study of kerosene ignition delay at high pressures [J]. Science China Physics ,Mechanics and Astronomy, 2012 , 55 （ 6 ）: 947 ⁃ 954 .

刘宇，孙震，罗睿，等 . CH 4 /RP⁃3航空煤油混合燃料燃烧特性的实验研究 [J]. 推进技术， 2018 ， 39 （ 5 ）: 1177 ⁃ 1186 .

LIU Yu , SUN Zhen , LUO Rui , et al . Experimental study on combustion characteristics of CH 4 /RP⁃3 kerosene mixed fuel [J]. Journal of Propulsion Technology , 2018 , 39 （ 5 ）: 1177 ⁃ 1186 . （in Chinese）

LIU Y X , YU D , TIAN D X , et al . An experimental and modeling study of oxidation of 1,2,4⁃trimethylcyclohexane with JSR [J]. Proceedings of the Combustion Institute , 2019 , 37 （ 1 ）: 437 ⁃ 444 .

LIU J , HU E J , ZENG W , et al . A new surrogate fuel for emulating the physical and chemical properties of RP⁃3 kerosene [J]. Fuel , 2020 , 259 : 116210.1 ⁃ 116210.9 .

GAO Z H , HU E J , XU Z H , et al . Low to intermediate temperature oxidation studies of dimethoxymethane/ n ⁃heptane blends in a jet⁃stirred reactor [J]. Combustion and Flame , 2019 , 207 : 20 ⁃ 35 .

WESTBROOK C K , PITZ W J , HERBINET O , et al . A comprehensive detailed chemical kinetic reaction mechanism for combustion of n⁃alkane hydrocarbons from n ⁃octane to n ⁃hexadecane [J]. Combustion and Flame , 2009 , 156 （ 1 ）: 181 ‑ 199 .

HERBINET O , MARQUAIRE P M , BATTIN⁃LECLERC F , et al . Thermal decomposition of n ⁃dodecane:experiments and kinetic modeling [J]. Journal of Analytical and Applied Pyrolysis , 2007 , 78 （ 2 ）: 419 ⁃ 429 .

OLCHANSKI E , BURCAT A . Decane oxidation in a shock tube [J]. International Journal of Chemical Kinetics , 2006 , 38 （ 12 ）: 703 ⁃ 713 .

ZEPPIERI S P , KLOTZ S D , DRYER F L . Modeling concepts for larger carbon number alkanes:a partially reduced skeletal mechanism for n ⁃decane oxidation and pyrolysis [J]. Proceedings of the Combustion Institute , 2000 , 28 （ 2 ）: 1587 ⁃ 1595 .

XI S H , XUE J , WANG F , et al . Reduction of large⁃size combustion mechanisms of n ⁃decane and n ⁃dodecane with an improved sensitivity analysis method [J]. Combustion and Flame , 2020 , 222 : 326 ⁃ 335 .

OEHLSCHLAEGER M A , STEINBERG J , WESTBROOK C K , et al . The autoignition of iso⁃cetane at high to moderate temperatures and elevated pressures:shock tube experiments and kinetic modeling [J]. Combustion and Flame , 2009 , 156 （ 11 ）: 2165 ⁃ 2172 .

WEBER B W , PITZ W J , MEHL M , et al . Experiments and modeling of the autoignition of methylcyclohexane at high pressure [J]. Combustion and Flame , 2014 , 161 （ 8 ）: 1972 ⁃ 1983 .

NAKAMURA H , DARCY D , MEHL M , et al . An experimental and modeling study of shock tube and rapid compression machine ignition of n‑ butylbenzene/air mixtures [J]. Combustion and Flame , 2014 , 161 （ 1 ）: 49 ⁃ 64 .

METCALFE W K , DOOLEY S , DRYER F L . Comprehensive detailed chemical kinetic modeling study of toluene oxidation [J]. Energy and Fuels , 2011 , 25 （ 11 ）: 4915 ⁃ 4936 .

MORRIS M D . Factorial sampling plans for preliminary computational experiments [J]. Technometrics , 1991 , 33 （ 2 ）: 161 ⁃ 174 .

CHANG Y C , JIA M , LI Y P , et al . Development of a skeletal mechanism for diesel surrogate fuel by using a decoupling methodology [J]. Combustion and Flame , 2015 , 162 （ 10 ）: 3785 ‑ 3802 .

ELLIOTT L , INGHAM D B , KYNE A G , et al . Genetic algorithms for optimisation of chemical kinetics reaction mechanisms [J]. Progress in Energy and Combustion Science , 2004 , 30 （ 3 ）: 297 ⁃ 328 .

METCALFE W K , BURKE S M , AHMED S S , et al . A hierarchical and comparative kinetic modeling study of C 1 -C 2 hydrocarbon and oxygenated fuels [J]. International Journal of Chemical Kinetics , 2013 , 45 （ 2 ）: 638 ⁃ 675 .

浏览量

下载量

CSCD

文章被引用时，请邮件提醒。

提交

工具集

关联资源

天然气氧化特性的实验与数值计算

增材制造螺旋圆管航空煤油热氧化结焦特性的试验研究

RP⁃3航空煤油与其模型燃料雾化特性的对比试验

基于三维接触摩擦单元的套齿连接解析建模研究

考虑多源不确定性的复合材料风扇叶片高周疲劳失效概率评估