ZHENG Yu-tong, ZHANG Pei-hong, MA Xin. Influence of nano-Al2O3 Dispersion on the Dielectric Properties of Silicone Rubber Composites[J]. 2016, 21(6): 84-89.
ZHENG Yu-tong, ZHANG Pei-hong, MA Xin. Influence of nano-Al2O3 Dispersion on the Dielectric Properties of Silicone Rubber Composites[J]. 2016, 21(6): 84-89.DOI: 10.15938/j.jhust.2016.06.016.
纳米Al2O3分散性对硅橡胶复合物介电性影响
摘要
为了研究纳米粒子的分散性与纳米AlO3/硅橡胶复合物介电性的关系
分别采用将纳米AlO3粉体与硅橡胶直接混合的方法和先将纳米AlO3粉体制备成浓度为10%的分散液
再将分散液与硅橡胶混合的方法制备了质量分数为1%、2%、3%和4%的纳米AlO3/硅橡胶复合物
利用透射电镜TEM表征纳米AlO3粒子在复合物中的分散性
可以看出
方法二制备的复合硅橡胶中纳米AlO3分散良好.测试了复合物的空间电荷特性、介电谱特性和电导电流特性
测试结果表明
方法二制备的复合硅橡胶中空间电荷积聚减少
载流子迁移率增加
相对介电常数和电导电流密度减小
电老化阈值增大
说明复合硅橡胶的介电性受纳米粒子分散性影响.
Abstract
To investigate the relation between nano-particles dispersion and the dielectric properties of AlO3/silicone rubber composite
two methods were adopted to prepare composites with nano-AlO3 loading of 1%
2%
3% and 4% respectively.The first method is to mix nano-AlO3 powders and silicone rubber by homogenizer(named method 1)
and the second one is to disperse nano-AlO3 powders in liquid
then mix the dispersion liquid with silicone rubber(named method 2).The transmission electron microscope(TEM) was used to observe the dispersion of nano-particles in the composites.It can be seen that in the samples prepared by method 2
nano-AlO3 dispersed well.Dielectric properties of space charge
dielectric spectroscopy and conduction current were test.The results show that good dispersion of nano-AlO3 in the silicone rubber could decrease the accumulations of space charge
increase carrier mobility
decrease permittivity and conduction current density and increase the electrical aging threshold of the composites.It was concluded that the dispersion of nano-AlO3 impacts on the dielectric properties of silicone rubber composites.