1. [1]哈尔滨理工大学材料科学与工程学院,黑龙江,哈尔滨,150040
2. [2]哈尔滨市香坊区疾病控制中心,黑龙江,哈尔滨,150000
纸质出版:2016
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陈宇飞, 楚洪月, 张清宇, 等. Al2O3改性MDI型聚氨酯弹性体制备及力学性能[J]. 哈尔滨理工大学学报, 2016,21(6):117-122.
CHEN Yu-fei, CHU Hong-yue, ZHANG Qing-yu, et al. Preparation and Mechanical Propertiesof MDI Polyurethane Elastomer Modified by Al2O3[J]. 2016, 21(6): 117-122.
陈宇飞, 楚洪月, 张清宇, 等. Al2O3改性MDI型聚氨酯弹性体制备及力学性能[J]. 哈尔滨理工大学学报, 2016,21(6):117-122. DOI: 10.15938/j.jhust.2016.06.022.
CHEN Yu-fei, CHU Hong-yue, ZHANG Qing-yu, et al. Preparation and Mechanical Propertiesof MDI Polyurethane Elastomer Modified by Al2O3[J]. 2016, 21(6): 117-122. DOI: 10.15938/j.jhust.2016.06.022.
为了提高聚氨酯(PU)弹性体机械强度
尝试用超临界乙醇处理的无机氧化铝(SCE-Al2O3)粒子改性以提高弹性体性能.以4
4-二苯基甲烷二异氰酸酯(MDI)、聚醚二醇(PPG)、二乙烯三胺(DETA)和环氧树脂(E-51)等为主要原料
采用预聚体酮连氮法合成了双组份聚氨酯弹性体
再用SCE-Al2O3改性
制备了Al2O3/PU弹性体.通过红外光谱(FT-IR)表征聚合物的结构;X射线衍射(XRD)表征SCE-Al2O3在基体中结晶峰的变化;扫描电镜(SEM)观察SCE-Al2O3在基体中的分散效果和结构;通过拉伸强度和断裂伸长率的变化分析改性前后的SCE-Al2O3对弹性体力学性能的影响.结果表明
未处理的Al2O3(unmodified-Al2O3)掺加量为质量分数1%、2%对弹性体拉伸强度的提高分别为19.22%
和10.02%;断裂伸长率也分别提高18.91%和8.96%.而2%SCE-Al2O3/PU弹性体的拉伸强度和断裂伸长率均为最佳
比纯PU和2%unmodified-Al2O3/PU分别提高了25.36%
26.37%和13.95%
15.98%.
Polyurethane elastomer(PU) has good mechanical properties
widely used in the construction
furniture and clothing.With its applications are more and more widely
the requirements of PU in mechanical performance were increasingly high
in order to reduce cost of production under the premise of improving the mechanical strength of the polyurethane elastomer.The inorganic alumina(Al2O3) particles modified by supercritical ethanol(SCE-Al2O3) were used to enhance the performance of elastomer in this paper.4
4-diphenyl methane diisocyanate(MDI)
polyether glycols(PPG)
diethylenetriamine(DETA) and epoxy resin(E-51) were used as the main raw materials and synthesized two-component polyurethane elastomer by the use of acetone link to nitrogen
and then modified its properties by SCE-Al2O3
synthesized Al2O3/PU elastomer.Infrared spectroscopy(FT-IR)and X-ray diffraction(XRD) was used to characterize structure of the materials and the extent of change in Al2O3 crystal substrate
scanning electron microscopy(SEM) was used to observe dispersion of the Al2O3 in the matrix and to analyse the Al2O3 effect on the mechanical property of elastic including of tensile strength and elongation at break.The results of experiments showed that there was a little improved in the tensile strength and the elongation at break when the unmodified-Al2O3 was added in 1wt% and 2wt%
that was 19.22%
10.02% and 18.91%
8.96%.The tensile strength and the elongation at break was best when the content of SCE-Al2O3 was 2wt%
that was 7.76 MPa and 254%
improved 25.36%
26.37% and 13.95%
15.98% than that of pure PU and 2wt% unmodified-Al2O3
respectively.
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