GUO Er-jun, ZHANG Zhi, FENG Yi-cheng, et al. Study on Refining of Mg-6Al Alloy by Mg-7Sm-4Al Refiner[J]. 2020, 25(6): 119-125.DOI: 10.15938/j.jhust.2020.06.017.
摘 要: 针对稀土化合物对 Mg-Al 合金的细化问题,通过向纯 Mg 中复合添加 Al 和 Sm 元素制得 Mg-7Sm-4Al 细化剂,研究了细化剂对 Mg-6Al 合金的细化效果,并设计了直接添加同等量 Al 和Sm 的对照实验。讨论了这俩种添加方式对 Mg-6Al 合金晶粒尺寸的影响。实验结果表明: 外添加 Mg-7Sm-4Al 细化剂可以很好的细化 Mg-6Al 合金。当 Mg-7Sm-4Al 细化剂的添加量质量分数为 36. 4% 时,Mg-6Al 合金的平均晶粒尺寸由原始的 126. 12 μm 细化到 75. 68 μm。细化机制是 Mg- 7Sm-4Al 中未溶解的 Al2 Sm 颗粒起到了异质形核作用,溶解的 Al 和 Sm 元素的溶质效应,二者协同 作用使合金细化。从直接添加 Al 和 Sm 的对照实验可以得出,添加质量分数为 0. 64% Sm 会使 Mg- 6Al 合金晶粒粗化,因为 Sm 元素具有去除氧化物杂质的作用,带走 Mg-Al 合金中富氧异质形核质 点,降低形核率。当 Sm 的添加量达到质量分数的 2. 55% 时,Sm 和 Al 生成具有异质形核能力的 Al2 Sm 颗粒,使合金细化。
Abstract
The Mg-7Sm-4Al refiner was prepared by adding Al and Sm elements to pure Mg,and the refiningeffect of the refiner on Mg-6Al alloy was studied. The comparative experiment was designed to directly add the same amount of Al and Sm. The effects of these two addition methods on the grain size of Mg-6Al alloy were discussed. The results showed that the addition of the Mg-7Sm-4Al refiner can refine the Mg-6Al alloy very well. When the addition amount of the Mg-7Sm-4Al was 36. 4% ,the average grain size of the Mg-6Al alloy was refined from the original 126. 12 μm to 75. 68 μm. The refiner mechanism was that the undissolved Al2 Sm particles in the Mg-7Sm- 4Al alloy act as a heterogeneous nucleation,soluble Al and Sm elements cause solute effects,and the two reasons together make the alloy refine. From the comparative experiment results of directly adding Al and Sm,it can be concluded that adding 0. 64% Sm could coarsen the grain of Mg-6Al alloy,due to Sm element removed oxide impurities,and took away the oxygen-rich heterogeneous in Mg-Al alloy,thus reducing the nucleation rate. When the addition amount of Sm reaches 2. 55% ,the alloy is refined,because Sm and Al formed Al2 Sm particles with heterogeneous nucleation ability.