1. 1哈尔滨理工大学 材料科学与工程学院,哈尔滨,150080
2. 2东北轻合金有限责任公司,哈尔滨,150060
纸质出版:2021
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赵明铭, 郭二军, 冯义成, 等. 基于JMatPro对2324铝合金析出相的热力学模拟计算[J]. 哈尔滨理工大学学报, 2021,26(6):112-117.
ZHAO Ming-ming, GUO Er-jun, FENG Yi-cheng, et al. Thermodynamic Simulation of Precipitation Phase Evolution in 2324 Aluminum Alloy by Jmat Pro[J]. 2021, 26(6): 112-117.
赵明铭, 郭二军, 冯义成, 等. 基于JMatPro对2324铝合金析出相的热力学模拟计算[J]. 哈尔滨理工大学学报, 2021,26(6):112-117. DOI: 10.15938/j.jhust.2021.06.015.
ZHAO Ming-ming, GUO Er-jun, FENG Yi-cheng, et al. Thermodynamic Simulation of Precipitation Phase Evolution in 2324 Aluminum Alloy by Jmat Pro[J]. 2021, 26(6): 112-117. DOI: 10.15938/j.jhust.2021.06.015.
2324铝合金具有优异的综合性能,尤其是高的损伤容限性能,作为结构材料在先进大飞机上得到广泛应用,其热处理工艺是保证高综合性能的关键。本文以工业用2324铝合金为研究对象,采用JMatPro软件模拟计算2324铝合金的平衡相组成、亚稳相、TTT/CCT曲线、等温时效相组成,并优化其热处理工艺参数。研究结果表明,2324铝合金在室温条件下的相组成为88.02% α(Al)、7.28% S(Al2CuMg)、2.45% Al6Mn、1.35% Al2Cu、0.63% E(AlCrMgMn)和0.27% Mg2Si,其中S相是主要的强化相;合金的亚稳相为S′相、Q′相和η′相,其中S′相为时效过程主要强化相;通过TTT曲线计算表明,在热处理过程中,GP区、η′、S′、η(MgZn2)、S相的鼻尖温度依次升高,分别为170、300、350、360、420℃,对应的孕育时间分别为5.45、40.91、15.23、920.62、305.83s。CCT曲线计算表明,在热处理过程中,GP区、η′、S′、η(MgZn2)、S相不析出的临界冷却速率分别为0.95、1.72、5.22、0.16,0.90℃/s;在190℃时效时,S′相的析出量较大,完全时效时间也较短。时效时间为5~10h时,强化相含量较高,GP区也有一定含量;因此,综合上述结果可以得出最佳的热处理工艺:固溶处理时,冷却介质的冷却速度大于5.22℃/s,试样固溶转移时间小于5.45s,时效的温度和时间分别设置为190℃,5~10h。
2324 aluminum alloy has excellent comprehensive performance
especially high damage tolerance performance As a structural material
it has been widely used in advanced large aircraft
and its heat treatment process is the key to ensure high comprehensive performance.This paper takes 2324 aluminum alloy for industrial use as the research object. The equilibrium phase composition
metastable phase
TTT/CCT curve and isothermal aging phase composition of 2324 aluminum alloy are simulated by JMatPro software
and the heat treatment process parameters are optimized. The results show that the phase composition of 2324 aluminum alloy at room temperature is 88.02% α(Al)
7.28% S(Al2CuMg)
2.45% Al6Mn
1.35% Al2Cu
0.63% E(AlCrMgMn) and 0.27% Mg2Si
among which S phase is the main strengthening phase.The metastable phase of the alloy is S′ phase
Q′ phase and η′ phase
among which S′ phase is the main strengthening phase during the aging process.The TTT curve calculation show that during the heat treatment
the tip temperatures of GP zone
η′
S′
η(MgZn2) and S phase increase successively
which are 170℃
300℃
350℃
360℃ and 420℃ respectively
and the corresponding incubation times are 5.45s
40.91s
15.23s
920.62s and 305.83s respectively The CCT curve calculation shows that the critical cooling rates of GP zone
η′
S′
η(MgZn2) and S phase without precipitation during heat treatment are 0.95℃/s
1.72℃/s
5.22℃/s
0.16℃/s and 0.90℃/s respectively.When aging at 190℃
the precipitation amount of S′ phase is larger
and the complete aging time is shorter.When the aging time is 5~10h
the strengthening phase content is higher
and there is also a certain content for GP zone.Therefore
by the above results
the optimal heat treatment process can be obtained: the cooling rate of the cooling medium is greater than 5.22℃/s in the solid solution treatment
the solid solution transfer time of the sample is less than 5.45s
and the aging temperature and time are respectively set at 190℃ and 5~10h.
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